Photopolymerization of acrylates by enzymatically synthesized PCL based macrophotoinitiator

NMR of enzymatically synthesized uniformly 13C15N-labeled DNA oligonucleotides.

A procedure for the enzymatic synthesis of uniformly 13C15N-labeled DNA oligonucleotides in milligram quantities for NMR studies is described. Deoxynucleotides obtained from microorganisms grown on 13C and 15N nutrient sources are enzymatically phosphorylated to dNTPs, and the dNTPs are incorporated into oligonucleotides using a 3'-5' exonuclease-deficient mutant of Klenow fragment of DNA polym...

Physical properties and structure of enzymatically synthesized amylopectin analogs

Origami by frontal photopolymerization

Origami structures are of great interest in microelectronics, soft actuators, mechanical metamaterials, and biomedical devices. Current methods of fabricating origami structures still have several limitations, such as complex material systems or tedious processing steps. We present a simple approach for creating three-dimensional (3D) origami structures by the frontal photopolymerization method...

Thermal stability and degradation kinetics of polyphenols and polyphenylenediamines enzymatically synthesized by horseradish peroxidase

−Various substituted phenols and phenylenediamines were enzymatically polymerized by horseradish peroxidase in 80% (v/v) organic solvents-aqueous buffer (100 mM sodium acetate, pH 5) mixtures with H2O2 as the oxidant. The thermal stability of the polymers was investigated by thermogravimetric analysis (TGA) and represented by the char yield (wt% of the initial polymer mass) after being heated a...

Chapter-3. Rheological Behavior of Starch-Polycaprolactone (PCL) Nanocomposite Melts Synthesized by Reactive Extrusion

3.1 Abstract Rheological behavior of reactively extruded starch-PCL nanocomposite blends was evaluated in an off-line capillary rheometer. Power law models for blends with different nanoclay volume fractions were developed using appropriate correction factors. Consistency coefficients K for blends containing starch were significantly higher than 100% PCL. Starch-PCL nanocomposite blends showed ...